OPTIX / Alfa Chemistry
YVO4 (Yttrium Orthovanadate)

YVO4 (Yttrium Orthovanadate)

Catalog NumberOPTIX00001

CategoryBirefringent Crystals

Description YVO4 serves a crucial purpose in the field of optical technologies due to its exceptional characteristics. This positive uniaxial crystal is produced using the Czochralski method, which results in excellent temperature stability, as well as robust physical and mechanical properties. YVO4 is particularly suited for optical polarizing components, owing to its extensive transparency range and significant birefringence. This makes it an outstanding synthetic alternative to traditional Calcite (CaCO3) and Rutile (TiO2) crystals. Its applications are diverse, encompassing fiber optic isolators, circulators, interleavers, beam displacers, and various other polarizing optics, providing superior performance across these technologies.
Density 4.22 g/cm3
Birefringence 0.2039 @1550 nm (ne-no)
Chemical Formula YVO4
Coating AR-Coating: R<0.2% @1550 nm or 1310 nm ± 40 nm
Crystal Class Positive uniaxial with no=na=nb, ne=nc
Crystal Structure Zircon Tetragonal, space group D4h
Dimension Tolerance Birefringent Wedges: Dimension Tolerance ±0.1mm, Wedge Angle Tolerance±0.1 °, Optical Axis Orientation ±0.5 ° ;
Beam Displacers: (W ± 0.05 mm) × (H ± 0.05 mm) × (L ± 0.1 mm).
Flatness λ/4 @633 nm
Hardness 5 Mohs (glass-like)
Hygroscopic Non-hygroscopic
Lattice Parameter a = b = 7.12 Å; c = 6.29 Å
Parallelism 20 arc sec
Perpendicularity ≤15 arc min
Refractive Index Birefringence (Δn = ne- no) and Walk-off Angle @ 45°(ρ):
no=1.9929, ne=2.2154, Δn=0.2225, ρ=6.04°@ 630 nm;
no=1.9500, ne=2.1554, Δn=0.2054, ρ = 5.72° @1300 nm;
no=1.9447, ne=2.1486, Δn=0.2039, ρ=5.69° @ 550 nm.
Sellmeier Equation no2=3.77834+0.069736 /(λ2-0.04724)-0.0108133 λ2
ne2=4.59905+0.110534 /(λ2 - 0.04813)-0.0122676λ2
Size Bulk/Finished YVO4 Crystals: up to Φ35 x 50 mm3 and Φ20 x 20 mm3;
Birefringent Wedges: 1.25 mm × 1.25 mm × 0. 5 mm with 13° or 15° wedge, π = 22.5 °;
Beam Displacers: 2.6 × 2.6 × 10 mm3, θ = 45°, Φ = 0°
Surface Quality 20/10 to MIL-PRF-13830B (Scratch/Dig)
Thermal Conductivity // C: 5.23 W/m/K; ⊥C: 5.10 W/m/K
Thermal Expansion Coefficient αa=4.43×10-6 /K; αc=11.37×10-6 /K
Thermal Optical Coefficient dna/dT = 8.5×10-6 /K; dnc/dT = 3.0×10-6 /K
Transparency Range 0.4 - 5 μm
Type Birefringent Crystals

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